Hongwu International Group Ltd, with HWNANO brand, is a high-tech enterprise focusing on manufacturing, research, development and processing of nanoparticles,nanopowders, micron powders.
Diamonds are the hardest naturally occurring minerals known to man. Even so, scientists are working to make them even tougher, in order to use the sparkling gems as tools for cutting.
Now, a team of researchers, led by Yongjun Tian and Quan Huang at Yanshan University in China, has created synthetic diamonds that are harder, meaning they are less prone to deformation and breaking, than both natural and other man-made diamonds.
To create these tougher-than-steel diamonds, the researchers used tiny particles of carbon, layered like onions, and subjected them to high temperatures and pressures. The resulting diamonds had a unique structure that makes them more resistant to pressure and allows them to tolerate more heat before they oxidize and turn to either gas (carbon dioxide and monoxide) or ordinary carbon, losing many of their unique diamond properties.
First, a bit about diamonds: Gem-quality diamonds are single crystals, and they are quite hard. But artificial diamonds used on tools are harder still. That’s because they are polycrystalline diamonds, or aggregates of diamond grains called domains, that measure a few micrometers or nanometers across. The grains help to prevent the diamond from breaking, as the boundaries act like small walls that keep chunks of diamond in place. The smaller the domains are, the stronger the diamond.
Tian’s team used the onionlike carbon Nitrides Nanoparticles to make diamonds with domains that are a few nanometers in size and are mirror images of each other. Such “nanotwinned” crystals are much harder than ordinary diamonds, by a factor of two.
The team tested the artificial diamond’s hardness by pressing a pyramid-shaped piece of diamond into the nanotwinned diamond. Tian’s group made a small indentation in their artificial diamond, applying pressures equivalent to nearly 200 gigapascals (GPa) about 1.9 million atmospheres. An ordinary natural diamond would crush under just half that pressure.
The team also tested how hot the nanotwinned diamond could get before oxidizing. In two different tests, they found that the ordinary diamond began to oxidize at about 1,418 and 1,481 degrees Fahrenheit (770 and 805 degrees Celsius), depending on the testing method. The nanotwinned diamonds didn’t oxidize until they reached 1,796 or 1,932 F (980 or 1,056C).
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